The examples given above represent only the simplest and most common coupling patterns seen in the 1H NMR.
A simple ethyl group displays a quartet and a triplet in the ratio 2:3; the chemical shift of the CH2 group is sensitive to the attached substituent and typically varies between d 4 (for oxygen) to d
2 (for a carbonyl).
An isopropyl group displays a septet (7 peaks) and a doublet in the ratio 1:6; again, the chemical shift of the CH2 group is sensitive to the attached substituent and typically varies between d 4 (for oxygen) to d
2 (for a carbonyl).
A 1,4-disubstituted aromatic compound displays two doublets in the ratio of 1:1, typically in the region around d 7.
In spite of the fact that there are three different types of hydrogens in a monosubstituted aromatic compound, the 1H NMR typically displays a single peak in the region around d 7. This is because the differences in chemical shift are typically small, as are the coupling constants.
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